W.A. Groen (Pim)

Prof. dr. Pim Groen

                                                                                                                              

Faculty of Aerospace Engineering, Room: NB 1.28

Kluyverweg 1
2629 HS Delft, The Netherlands
Tel: +31 (0)15 2781607
Fax. +31 (0)15 2784472
Email: w.a.groen@remove-this.tudelft.nl

 

 

 

Biography

 

In 1987 I graduated at Leiden University on the field of Solid State Chemistry working on crystal structures of perovskites. Hereafter I worked two years as AIO2 also in Leiden. I did my PhD in 1990 in the field of ceramic superconductors. I joined Philips Research in 1987 where I worked in Eindhoven on inorganic materials for electronic applications and later in Philips Forschung Aachen (Germany) on electronic ceramics, including piezoelectric ceramics. When Philips stopped its activities in the field of passive components I joined Morgan Electroceramics as R&D manager in 2002 where I was responsible for projects with customers to implement piezo-technology into their products. Furthermore, I led a project on a new production line for the making of multilayer piezoelectric actuators. From January 2008 until September 2011, I was department head of the group Materials Performance at TNO Science and Industry. Since 2011 I am working at the Holst Centre as programme manager for the programs “Large Area Printing” and “Printed Conductive Structures”. In 2009, I joined the Novel Aerospace Materials (NovAM) group as a visiting scientist starting new activities in the field of Smart Materials & Sensors. Since 2012 I am a part time full Professor at the faculty of Aerospace Engineering on the chair “SMART Materials” next to my work at the Holst Centre.

 

Current projects

Smart materials 

More information on the facilities within the smart materials portion of the NovAM group can be found here.

 

Light Touch Matters

February 2013 marked the start of Light.Touch.Matters, in which designers and material researchers join forces to develop a fully-new generation of smart materials that can sense touch and respond with luminescence. The base technologies are novel piezo plastics and flexible OLEDs. Being thin, flexible and formable, these light touch materials promise to revolutionize product interface design by integrating luminescence and touch in such a way that eventually the product becomes the interface. During the project, various technology demonstrators will be developed to demonstrate the potential of such novel interface technologies, principally within the domain of care, although opportunities for spin-off to other domains (e.g. automotive) will also be addressed. Light.Touch.Matters is a unique cooperation between product designers and material scientists, with 17 partners from 9 EU countries. It is funded through a grant in the European Commission’s 7th Framework Programme and will run for 3.5 years until July 2016. See more at: http://www.light-touch-matters-project.eu/ltm-what/#sthash.e9nwc65r.dpuf

 

 

 

 

Novel concepts for piezoelectric composites in sensor devices and energy harvesting

Piezoelectric sensors offer tremendous benefits for many sensing applications, by being able to convert mechanical energy to electrical energy. Applications range from pressure switches to damage detection systems. In addition piezoelectric materials are well suited as electrical energy generators (power harvesting systems). State-of-the-art piezoelectric materials such as PZT ceramics and PVDF polymers possesses several drawbacks in other areas, which limits their use as successful sensor and energy scavenger materials. Piezoelectric composites have the potential of overcoming many of these drawbacks, but generally suffer from compromised piezoelectric properties, ultimately lowering the output signal. Novel concepts are being explored to exploit the composites advantages, while employing novel techniques to increase piezoelectric signal output from these materials to a higher level. An important topic in the aviation industry is Structural Health Monitoring. Currently, the safety of airplanes is secured by inspections at regular intervals which are optical or by ultrasound. In the ideal case, sensors for SHM will be built into the airframe and connected to a network. In case of difficult to reach places wireless sensors will be incorporated in the structural system. However, the lifetime of such systems is limited by the lifetime of the batteries which are used to power these systems. Solution for this can be found by energy scavenging or harvesting systems. Part of these systems are also based on piezoelectric materials by the application is still very limited. Both energy harvesting systems and sensors for SHM will be part of the new research.  

 

 

Visiting Ian Reaney’s group in 2012.

 

 

 

Visiting the Holst Centre in 2014, with NovAM master's students, as part of the course on: Sensor materials (AE4ASM104).

 

 

Courses at TU Delft

 

AE4ASM002 - Designing Materials with Aerospace Specific Properties

AE4ASM104 - Sensor Materials

 

 

List of Publications

 

Books

1.              Jan Holterman and Pim Groen;

                 An Introduction to Piezoelectric Materials and Components,

                 First published June 2012, ISBN 978-90-819361-0-1, NUR 971;

                 Published by: Stichting Applied Piezo, P.O. Box 4176, 7320 AD Apeldoorn, the Netherlands

 

2.              Jan Holterman and Pim Groen;

                 An Introduction to Piezoelectric Materials and Applications,

                 First published April 2013, ISBN: 978-90-819361-1-8;

                 Published by: Stichting Applied Piezo, P.O. Box 4176, 7320 AD Apeldoorn, the Netherlands

 

Book chapter

1.              Sybrand van der Zwaag, Daan A. van den Ende and Wilhelm Albert (Pim) Groen,

                 Sensing and Energy Harvesting Novel Polymer Composites (Chapter 16) in Materials Experience;

                 In: Fundamentals of Materials and Design,

                 Edited by Elvin Karana, Owain Pedgley Valentina Rognoli,

                 First published 2014, I Butterworth-Heinemann, Oxford, OX5 1GB, UK, IBN: 978-0-08-099359-1

 

                                

Academic Publications (peer reviewed journals)

82.           H. Khanbareh, B. Schelen, S. van der Zwaag and W.A. Groen, 

               “A multi-mode temperature oscillation instrument based on discrete sampled data and mathematical lock-in method to determine
                pyroelectric properties of materials at low frequencies,“

                Review of Scientific Instruments, AIP (2015)

 

81.           Sander Kommeren, Michiel J.J. Coenen, Tamara M. Eggenhuisen, Thijs W. L. Slaats, H. Gorter and P. Groen,

               “Combining solvents and surfactants for inkjet printing PEDOT:PSS on P3HT/PCBM in organic solar,“

                J. Phys. Chem. C, submitted Feb. 2015.

 

80.           H. Khanbareh, D.B. Deutz, S. van der Zwaag and W.A. Groen,
               “Positioning the properties of new functional granular composites for piezo- and pyroelectric energy harvesting against those of
                monolytic materials,“

                Journal of Intelligent Material Systems and Structures, accepted 2015

 

79.           N. K. James, T. Comyn, D. A. Hall, L. Daniel, A. K. Kleppe,  S. van der Zwaag and W.A. Groen
               "Analysis of the state of poling of lead zirconate titanate (PZT) particles in an Zn-ionomer composite using high energy synchrotron
                X-ray diffraction,“
                Eur. Jour. Ceram Soc., submitted Nov. 2014.

 

78.           T.M. Eggenhuisen, Y. Galagan, A. Biezemans, T. Slaats, P. Voorthuijzen, S. Kommeren, S. Shanmugam, J.P. Teunissen, A. Hadipour,
                S.C. Veenstra, M.J.J. Coenen, J. Gilot,  R. Andriessen and W.A. Groen, 
               ”High Efficiency, Fully Inkjet Printed Organic Solar Cells with Freedom of Design,”
                Journal of Materials Chemistry A, 2015, DOI: 10.1039/C5TA00540J.

 

77.           D.B. Deutz, E. Tempelman, S. van der Zwaag and W.A. Groen,

               “Piezoelectric lead zirconium titanate composite touch sensors for integration with flexible OLED technology, “

                Ferroelectrics, 2015, DOI: 10.1080/00150193.2015.1012389.

 

76.           H. Khanbareh, S. van der Zwaag and W.A. Groen,

               “Piezoelectric and pyroelectric properties of conductive polyethylene oxide-lead titanate composites,“

                Smart Materials and Structures, Aug. 2015, accepted.

 

75.           Robert Abbel, Pit Teunissen, Jasper Michels and Pim Groen,

               "Narrow Conductive Structures with High Aspect Ratios Through Single-Pass Inkjet Printing and Evaporation-Induced Dewetting,"

                Advanced Engineering Materials, 2014, DOI: 10.1002/adem.201400339.

 

74.           Daan van den Ende, Rob Hendriks, Romain Cauchois and Wilhelm Albert Groen,

               “Large Area Photonic Flash Soldering of Thin Chips on Flex Foils for Flexible Electronic Systems: In Situ Temperature Measurements
                and Thermal Modelling,“

                Electron. Mater. Lett., Vol. 10, No. 6 (2014), pp. 1175-1183. (DOI: 10.1007/s13391-014-4222-3)

 

73.           Daan A. van den Ende, Rob Hendriks, Romain Cauchois, Roel H. L. Kusters, Maarten Cauwe, Wilhelm A. Groen and Jeroen van den Brand,

               "Photonic Flash Soldering of Transactions on components, packaging and manufacturing technology,"

                Packaging and manufacturing technology, Vol. 4, No. 11, November, 2014.

 

72.           Callum A. Lamont, Tamara M. Eggenhuisen, Michiel J.J. Coenen Thijs W.L. Slaats, Ronn Andriessen and Pim Groen,

               “Tuning the viscosity of halogen free bulk heterojunction inks for inkjet printed organic solar cells,“

                DOI: 10.1016 /j.orgel.2014.10.052

 

71.           Y. Galagan, S. Shanmugam, J.P. Teunissen, T.M. Eggenhuisen, Tim Van Gijseghem, W.A. Groen and R. Andriessen,
               “Evaluation of PEDOT:PSS and inkjet printed back electrode for organic solar cells with inverted architecture,”

                Solar Energy Materials & Solar Cells 130 (2014) 163–169.

 

70.           Robert Abbel, Pit Teunissen, Eric Rubingh, Tim van Lammeren, Romain Cauchois, Marcel Everaars, Joost Valeton,
                Sjoerd van de Geijn and Pim Groen,

               “Industrial Scale Inkjet Printed Electronics Manufacturing – Production Up-Scaling from Concept Tools to a Roll-to-Roll Pilot Line,”

                Transl. Mater. Res. 1 (2014) 015002 doi:10.1088/2053-1613/1/015002.

 

69.           Tamara M. Eggenhuisen, Michiel J.J. Coenen, Thijs W.L. Slaats, Harrie Gorter, Jörgen Sweelssen and Pim Groen,

               “Large Area Inkjet Printing for Organic Solar Cells and OLEDs using on-Halogenated Ink Formulations,"

                DOI: http://dx.doi.org/10.2352/ J.ImagingSci.Technol.2014.58.4.040402

 

68.           H. Khanbareh, S. van der Zwaag and W.A. Groen,

               “Effect of dielectrophoretic structuring on piezoelectric and pyroelectric properties of lead titanate-epoxy composites,”

                Smart Materials and Structures, vol. 23, p. 105030, 2014.

 

67.           T. M. Eggenhuisen, Y. Galagan, E.W.C. Coenen, W.P. Voorthuijzen, T. Slaats, S. Shanmuganam, M.J.J. Coenen,
                R. Andriessen and W.A. Groen,

               “Digital Fabrication of Organic Solar Cells by Inkjet Printing using non-Halogenated Solvents,”

                Solar Energy Mater. 2014,  10.1016/j.solmat.2014.12.014

 

66.           M.J.J. Coenen, M.W.L. Slaats, T.M. Eggenhuisen, H. Gorter and W.A. Groen,

               “Inkjet printing the three organic device layers of two-colored OLEDs,”

                Thin Solid Films, accepted Jan. 2015.

 

65.           N. K James, U. Lafont, S. van der Zwaag and W.A. Groen,

               "Piezoelectric and mechanical properties of fatigue resistant, self healing PZT-ionomer composites,"

                Smart Materials and Structures. 23 (2014) 055001 (9pp.).

 

64.           D.A. van den Ende, H.R. Fischer, W.A. Groen and S. van der Zwaag,

               “Switchable friction of piezoelectric composite-silicon wafer contacts, ”

                Appl. Phys. Lett. 102, 14, 141603, DOI: 10.1063/1.4801459 (2013).

 

63.           H.J. van de Wiel, Y. Galagan, T.J. van Lammeren, J.F.J. de Riet, J. Gilot, M.G.M. Nagelkerke, R.H.C.A.T. Lelieveld, S. Shanmugam,

                A. Pagudala, D. Hui, W.A. Groen,

               “R2R embedded conductive structures integrated into OPV devices, “

                Nanotechnology 24, 48, 484014.

 

62.           H. Gorter, M.J.J. Coenen, M.W.L. Slaats, M. Ren, W. Lu, C.J. Kuijpers, W.A. Groen,

               “Large Area Coating via Inkjet Printing for Printed OLED,”

                Thin Solid Films 532, 11-15 (2013).

 

61.           D. A. van den Ende, R. A. Maier, P. L. M. J. van Neer, S. van der Zwaag, C. A. Randall, and W. A. Groen,
               “Modeling and characterization of dielectrophoretically structured piezoelectric composites using piezoceramic particle inclusions with 
                high aspect ratios,”
                Journal of Applied Physics 113, 034103 (2013); doi: 10.1063/1.4775815.

 

60.           Nijesh Kunnamkuzhakkal James, Daan A. van den Ende, Ugo Lafont, Sybrand van der Zwaag and Wilhelm A. Groen,

               "Piezoelectric and mechanical properties of structured PZT–epoxy composites,"

                J. Mater. Res. 28 (2013) 635-641.

 

59.           Robert Abbel, Tim van Lammeren, Rob Hendriks, Jeroen Ploegmakers, Erwin R. Meinders, and Wilhelm A. Groen,

               "Photonic sintering of silver nanoparticle inks – a fast and convenient method for the production of highly conductive structures on foil,"

                MRS Communications (2012), 1 of 6, doi:10.1557/mrc.2012.28.

 

58            D.A. van den Ende, S.E. van Kempen, X. Wu, W.A. Groen, C.A. Randall, S. van der Zwaag,

               “Dielectrophoretically structured piezoelectric composites with high aspect ratio piezoelectric particles inclusions,”

                J. Appl. Physics 111, 124107 (2012).

 

57.           D. A. van den Ende, W.A. Groen and S. van der Zwaag,

               “Robust piezoelectric composites for energy harvesting in high strain environments,”

                Journal of Intelligent Material Systems and Structures 2012.

 

56.           D. A. van den Ende, H. J. van de Wiel, W .A. Groen and S. van der Zwaag,

               “Direct strain energy harvesting in automobile tires using piezoelectric PZT-polymer composites,”

                Smart Materials and Structures 21 015011 (2012).

 

55.           R. Mikkenie, O. Steigelmann, and W.A. Groen,

               "A quick method to determine the capacitance characteristics of thin layer X5R multilayer capacitors,”

                Eur. J. of Ceram 132,167-173 ( 2012).

 

54.           D.A. van den Ende, W.A. Groen, S. van der Zwaag,

               "The effect of calcining temperature on the properties of 0-3 piezoelectric composites of PZT and a liquid crystalline thermosetting polymer “,

                J. Electroceramics  27, 13-19 (2011).

 

53.           D.A. van den Ende, W.A. Groen and S. van der Zwaag,

               “Development of temperature stable charge based piezoelectric composite quasi-static pressure sensors“,

                Sensors and Actuators -Physical 163, 25-31 (2010).

 

52.           D.A. van den Ende, B. Bory, W.A. Groen, S. van der Zwaag,

               “Piezoelectric properties of quasi-1-3 composites by dielectrophoresis,”

                Integrated Ferroelectrics 114, 108-118 (2010).

 

51.           W.A. Groen, K. Prijs and S. Saeed,

               “Dependence of piezoelectric properties on layer thickness for multilayer actuators”, 

                Integrated Ferroelectrics 115, 132-141 (2010).

 

50.           R. Mikkenie, W.A. Groen and R. van der Drift,

               “Diffusion of silver during sintering in high permittivity COG dielectrics,” 

                Integrated Ferroelectrics 114, 72-80 (2010).

 

49.           D.A. van den Ende, B.F. Bory, W.A. Groen, S. van der Zwaag,

               “Improving the d33 and g33 properties of 0-3 piezoelectric composites by dielectrophoresis,”

                J. Appl. Physics 107, 024107 (2010).

 

48.           D. Irimia, D. Dobrikov, R. Kortekaas, H. Voet, D. A. van den Ende, W. A. Groen and M. H.M. Janssen,

               “A short pulse (7 ¹s FWHM) and high repetition rate (DC-5 kHz) cantilever piezo valve for pulsed atomic and molecular beams,”

                Review of Scientific Instruments 80, 113303 (2009).

 

47.           D.A. van den Ende, B. Bos, W.A. Groen and L.M.J.G. Dortmans,

               ”Lifetime of piezoelectric multilayer actuators: Interplay of material properties and actuator design,”

                J. Electroceramic 22, 163 (2009).

 

46.           D.A. van den Ende, B. Bos and W.A. Groen,

               “Non-linear electromechanical behaviour of piezoelectric bimorph actuators: influence on performance and lifetime,”

                J. Electroceramics 22, 185 (2009).

 

45.           M.D. Snel, W.A. Groen and G. de With,

              “New piezoelectric ceramics in system Bi(Mg0.75W0.25O3 – PbTiO3,”

                J. Europ. Ceram. Soc. 26, 89 (2006).

 

44.           M.D. Snel, W.A. Groen and G. de With,

               “Investigation of the piezoelectric system (1-x)Bi(Mg1/2Ti1/2)O3 – x PbTiO3,”

                J. Europ. Ceram. Soc. 25, 3229 (2005).

 

43.           W.A. Groen,  C. Metzmacher, V. Zaspalis,  P. Huppertz  and S. Schuurman ,

               “Aging of NTC Ceramics in the system Mn-Ni-Fe-O,”

                Eur. J. Ceram Soc. 21, 1793 (2001).

 

42.           H.A.M. van Hal, W.A. Groen, S. Maassen W.C. Keur,

               “Mechanochemical synthesis of BaTiO3, Bi0.5Na0.5TiO3 and Ba2NaNb5O15 dielectric ceramics,”

                J. Europ.Ceram. Soc. 21, 1689 (2001).

 

41.           W.A. Groen, C. Metzmacher, P. Huppertz  and S. Schuurman,

               “Aging of NTC Ceramics in the system Mn-Ni-Fe-O,”

                Journal of Electroceramics 7, 77 (2001).

 

40.           C. Metzmacher, W.A. Groen and I.M. Reaney,

               “Microstructure and Electrical properties of Mn-Ni-In Spinels,”

                Phys. Status Solidi (a) 181:2, 369 (2000).

 

39.           C. Metzmacher, R. Mikkenie and W.A. Groen,

               “Indium containing ceramics with negative temperature coefficient characteristic,”

                Eur. J. Ceram. Soc 20, 997 (2000).

 

38.           W.A. Groen, V. Zaspalis and S. Schuurman,

               “Aging of NTC ceramics investigated by magnetic measurements,”

                J.Mater. Sci. Lett. 18, 1233 (1999).

 

37.           Wen-Hsi Lee, W.A. Groen, Herbert Schreinemacher and Detlev Hennings,

               “Dysprosium doped dielectric material for sintering in reducing atmosphere,”

                J. of Electroceramics 5, 31 (2000).

 

36.           M.J. van Bommel, W.A. Groen, H.A.M. van Hal, W.C. Keur and T.N.M. Bernards,

               “The electrical and optical properties of thin layers of nano-sized antimony doped tinoxide particles,”

                J. Mater Sci 34, 4803 (1999).

 

35.           W.A. Groen, M.J. Kraan, P.F. van Hal, N. Sweegers and G. de With,

               "Preparation and properties of ALCON ceramics,"

                J. Mater. Sci. 30, 475 (1995).              

 

34.           W.A. Groen, M.J. Kraan, P.F. van Hal and A.E.M. De Veirman,

               "A new diamond related compound in the system Al2O3 Al4C3 AlN,"

                J. Sol. State Chem., 120, 211.

 

33.           H.T. Hintzen, R.Bruls, A. Kudyba, W.A. Groen and R. Metselaar,

               "Powder preparation and densification of MgSiN2 ,”

                Ceramic Transactions, 51, 585 (1995).

 

32.           M.A. van Veenendaal, G.A. Sawatzky and W.A. Groen,

               "Electronic structure of Bi2Sr2Ca1 xYxCu2O8+δ: Cu 2p x ray photoelectron spectra and occupied and unoccupied low energy states,"

                Phys. Rev. B49, 1407 (1994).

 

31.           H.T. Hintzen, W.A. Groen, M.J. Kraan, R. Metselaar,

               "Hot pressing of MgSiN2 ceramics,"

                J. Mater. Sci. Lett. 13, 1314 (1993) .

 

30.           W.A. Groen, M.J. Kraan and G. de With,

               "New ternary nitride ceramics: CaSiN2," 

                J. Mater. Sci., 29, 3161 (1994).

 

29.           W.A. Groen, M.J. Kraan and G. de With,

                "Preparation, microstructure and properties of MgSiN2 ceramics,"

                J. Eur. Cer. Soc. 12, 413 (1993).

 

28.           W.A. Groen and P.F. van Hal,

               "High temperature electrical conductivity of AlN ceramics,"

                Britisch Ceramic Transactions 93, 192 (1994).

 

27.           T.A.M. Haemers, D.J.W. IJdo, W.A. Groen, H.A.M. van Hal and R.B. Helmholdt,

                "Structure detemination of Praseodymium Hexaaluminate,"

                Mat. Res. Bull. 28, 111 (1993).

 

26.           W.A. Groen, J.L. van Lierop and A. Roosen,

                "Electrical and thermal conductivity of AlN ceramics doped with beryllium and oxygen,"

                J. Mater. Sci. Lett. 12, 1224 (1993).

 

25.           W.A. Groen, J.G. van Lierop and J.M. Toonen,

                "Electrical conductivity of AlN ceramics at High Temperatures,"

                J. Eur. Ceram. Soc. 11, 353 (1993).

 

24.           A.J. Smits, W.J. Elion, W.A. Groen, L.J. de Jongh and J.M. van Ruitenbeek,

               "Transport properties of Bi2Sr2 xLaxCuO6+δ,"

               Physica C199, 276 (1992).

 

23.           M.A. van Veenendaal, R. Schlatmann, W.A. Groen and G.A. Sawatzky,

                "Doping dependance of the chemical potential in Bi2Sr2Ca1 xYxCu2O8+δ,"

                Phys. Rev. B47 , 446 (1993).

 

22.           A.J. Smits, W.J. Elion, W.A. Groen, L.J. de Jongh and J.M. van Ruitenbeek,

                "Transport properties of Bi2Sr2 xLaxCuO6+δ,"

                Japanese Journal of Applied Physics, Part 1, 31, 276 (1992).

 

21.           H.W. Zandbergen, W.A. Groen, A. Smit and G. van Tendeloo,

                "Structure and properties of (Bi,Pb)2Sr2(Ca,Y)Cu2O8+δ,"

                Physica C168, 426 449 (1990).

 

20.           H.B. Brom, D. Reefman, J.C. Jol, D.M. de Leeuw and W.A.Groen,

                "205Tl NMR in Tl2Ba2CuO6 and the t J model,"

                Phys. Rev. B41, 7261 (1990).

 

19.           D.M. de Leeuw, W.A. Groen, L.F. Feiner and E.E. Havinga,

               "Correlation between the superconducting transition temperature and the crystal structure of high Tc cuprate compounds,"

                Physica C166, 133 (1990).

 

18.           W.A. Groen, D.M. de Leeuw and G.P.J. Geelen,

                "Hole concentration and Tc in Bi2Sr2CuO6+δ,"

                Physica C165, 305 (1990).

 

17.           D.M. de Leeuw, W.A. Groen, J.C. Jol, H.B. Brom and H.W. Zandbergen,

                "Hole doping in Tl2Ba2CuO6+δ  (Tc=0 80K) investigated by 205Tl nuclear magnetic resonance,"

                Physica C166, 349 (1990).

 

16.           H.W. Zandbergen and W.A. Groen,

                "New superstructures in as synthezised and in situ heated (Bi,Pb)2Sr2YCu2O8+δ,"

                Physica C166, 282 (1990).

 

15.           W.A Groen, D.M. de Leeuw and L.F. Feiner,

                "Hole concentration and Tc in Bi2Sr2CaCu2O8+δ,"

                Physica C165, 55 (1990).

 

14.           W.A. Groen, D.M. de Leeuw and G.M. Stollman,

                "Oxygen content, lattice constants and Tc of Bi2Sr2 xLaxCuO6+δ with 0.0 < x < 1.0,"

                Sol. State Comm. 72, 697 (1989).

 

13.           W.A. Groen and D.M. de Leeuw,

               "Oxygen content, lattice constants and Tc of Bi2Sr2CaCu2O8+δ,"

                Physica C159, 417 (1989).

 

12.           H.W. Zandbergen, W.A. Groen, G. van Tendeloo and S. Amelinckx,

                "High resolution electron microscopy and electron diffraction on Bi2Sr2 xLaxCanCu1+nO6+2n+δ,"

                Appl. Phys. A48, 305 (1989).

 

11.           W.A. Groen, R. Steens, H.W. Zandbergen, M.W. Dirken, F.M. Mulder and R.C. Thiel,

                "Substitution of calcium by rare earth elements in the high Tc superconductor Bi2Sr2CaCu2O8+δ,"

                J. of the Less Common Metals 155, 133 (1989).

 

10.           S. Olivier, W.A. Groen, C. van der Beek and H.W. Zandbergen,

                "On the solid solutions in the systems Bi2Sr2Ca1 xYxCu2O8+δ, Bi2Sr2 xLaxCaCu2O8+δ and Bi2Sr2Y1 xCexCu2O8+δ,"

                Physica C157, 531 (1989).

 

9.              H.W. Zandbergen, W.A. Groen, F.C. Mijlhoff, G. van Tendeloo and S. Amelinckx,

                 "Models for the modulation in A2B2CanCu1+nO6+2n, A, B=Bi,Sr or Tl, Ba and n=0,1,2,"

                 Physica C156, 325 (1988).

 

8.              W.A. Groen and H. W. Zandbergen,

                 "A study of Bi2Sr2 xLaxCuO6+δ with X ray and electron diffraction,"

                 Sol. State Comm. 68, 527 (1988).

 

7.              R.A. Zacher, H.W. Zandbergen, J. van den Berg, W.A. Groen, A.A. Menovsky, P.H. Kes and J.A. Mydosh,

                 "Properties and structure of the new high temperature superconductor: Ca Sr Bi Cu O,"

                 Bull. of the Am. Phys. Soc. 33, 1370 (1988).

 

6.              W.A. Groen and D.J.W. IJdo,

                 "Distrontium Diantimonate (V). A Rietveld Refinement of Neutron Powder Diffraction Data,"

                 Acta. Cryst. C44, 782 (1988).

 

5.              H.W.Zandbergen, P.Groen, G.vanTendeloo,J. van Landuyt and S.Amelinckx,

                 "Electron diffraction and electron microscopy of the high Tc superconductive phase in the Bi Ca Sr Cu O system,"

                 Sol. State. Comm. 66, 397(1988).

 

4.              W.A. Groen, F.P.F. van Berkel and D.J.W. IJdo,

                 "Trineodynium Ruthenate (V). A Rietveld Refinement of Neutron Powder Diffraction Data,"

                 Acta. Cryst. C43, 2262 (1987).

 

3.              P.A. Seinen, F.P.F. van Berkel, W.A. Groen and D.J.W. IJdo,

                 "The ordered perovskite system Ln2NiRuO6,"

                 Mat. Res. Bull. 22, 535 (1987).

 

2.              W.A. Groen and D.J.W. IJdo,

                 "The Monoclinic Perovskites Sr2CaUO6 and Ba2SrUO6. A Rietveld Refinement of Neutron Powder Diffraction Data,"

                 Acta. Cryst. C43, 1033 (1987).

 

1.              W.A. Groen, F.P.F. van Berkel and D.J.W. IJdo,

                 "Dineodynium Magnesium Titanate(IV). A Rietveld Refinement of Neutron Powder Diffraction Data,"

                 Acta. Cryst. C42, 1472 (1986).

 

                                

Conference Publications

 

C1.    W.A. Groen, M.J. Kraan, G. de With and M.PA. Viegers,
         "New covalent ceramics: MgSiN2,"
         Mat. Res. Soc. Proc. Vol. 327 (1994) 239.

 

C2.    H.A.M. van Hal and W.A. Groen,
         "Powder preparation of inorganic materials by spray drying,",
         Proceeding Electroceramics IV, Aachen, Germany (1994) 1339.

 

C3.    G. de With and W.A. Groen,
         "Thermal conductivity estimates for new (oxy)‑nitride ceramics,"
         Fourth Euro Ceramics, Vol. 3 (1995).405.

 

C4.    W.A. Groen, M.J. Kraan, P.F. van Hal and G. de With,
         "New high thermal conductivity ceramics,"
         Fourth Euro Ceramics, Vol. 3 (1995) 343.

 

C5.    W.A. Groen and V. Sillen, 
         High temperature thermistor based on doped samarium oxide,
         Ceramic Transactions, 90, 65 (1998).

 

C6.    G.D.C. Csete de Györgyfalva, I.M. Reaney, C. Metzmacher and W.A. Groen,
         ”Domain structure and tetragonality in manganese based spinels,”
         Electron Analysis Group Conference, Sheffield/UK 161, 529 (1999).

 

C7.    Albrecht Kraus, Bernd Rausenberger and W.A. Groen,
         “CERALIGHTTM – A new superior cold cathode fluorescent lamp,”
         Proceeding of the Ninth International Symposium on the Science and technology of Light Sources, Ed. Rolf S. Bergman,
         Published by Cornell University Press, Ithaca, NY, 152L (2001).

 

C8.    M. Ren, W. Lu, H. Gorter and W.A. Groen,
         “Large Area Coating via inkjet printing for Flexible Electronics ”
         ICCG9 (2012), isbn978-90-5986-404-7, Ed. H.A. Meinema, C.I.M.A. Spee, 75-80 (2012).

 

C9.    J. Gabel, H.A.J.M. Andriessen, I. Yakimets and W.A. Groen,
         “Patterning in Roll-to-Roll printing and coating technology",
         ICCG9 (2012), isbn978-90-5986-404-7, Ed. H.A. Meinema , C.I.M.A. Spee, 61-66 (2012).

 

C10.  J. Gabel, P. Rensing, E. Lutz, and P. Groen,
         “Spray-coating of functional layers of OLED and OPV”,
         ICCST2012. (16th International Coating Science and Technology Symposium, 2012, G Nichols, M (Eds.), Atlanta: ISCSTA),

 

C11.  Jaquelien van den Boomen, Marcel Everaars, Robert Abbel, Peter Spoor, Pim Groen,

         "Silver-based conductive inkjet inks for printed electronic applications",
         2012 E-MRS Spring Meeting.

 

C12.  Lafont, UL, Kunnamkuzhakkal James, N, Groen, WA, Zeijl, HW van & Zwaag, S van der, 
         "Self-healing composites with oriented fillers."
         In GB McKenna (Ed.), (2012) Proceedings of the 15th International Conference on Deformation, 

         Yield and Fracture Polymers (pp. 379-382). Eindhoven: Eindhoven University of Technology

 

C13.  Juliane Gabel, Jeroen Smulders, Pim Groen,
         “Atmospheric plasma printing  - potential and challenges of plasma on demand,“ 
         SVC Techcon 2013.

 

C14.  Tamara M. Eggenhuisen, Michiel J.J. Coenen, Thijs W.L. Slaats, Harrie Gorter, Jörgen Sweelssen and Pim Groen,
         "Large Area Inkjet Printing for OPV and OLED Applications Using Non Halogenated Ink Formulations",  
         ECS 2013.

 

C15.  Tamara M. Eggenhuisen, Michiel J.J. Coenen, Thijs W.L. Slaats, Harrie Gorter, Jörgen Sweelssen, Pim Groen,
         "Large Area Inkjet Printing for Organic Solar Cells and OLEDs using on-Halogenated Ink Formulations", 
         NIP & Digital Fabrication Conference, 2013 International Conference on Digital Printing Technologies. Pages 1-252. , pp. 203-205(3).

 

C16.  Pit Teunissen, Eric Rubingh, Tim van Lammeren, Robert Abbel, Sjoerd van de Geijn, Pim Groen,
         "Towards high speed inkjet printed electronics – Technology transfer from S2S to R2R production", 
         NIP & Digital Fabrication Conference, 2013 International Conference on Digital Printing Technologies, pp. 484-488(5), IBSN: 978-0-89208-306-0

 

C17.  Tamara M. Eggenhuisen, Yulia Galagan, Anne Biezemans, Michiel Coenen, Jan Gilot, Pim Groen and Ronn Andriessen,
         "Organic Photovoltaic Cells with All Inkjet Printed Layers and Freedom of Form", 

         PVSEC2014, DOI:10.1109/ PVSC.2014.6925523.

 

C18.  Pim Groen, Nijesh James, Hamideh Khanbareh, Daniella Deutz and Sybrand van der Zwaag,
         “New functional materials based on electroceramic composites,”
         International Conference on Electroceramics, Proceedings ICE2013, Brazil.

 

C19.  Pit Teunissen, Robert Abbel, Jasper Michels, Pim Groen,
         "Breaking the Limits of Line Width and Aspect Ratio for Inkjet Printed Conductive Lines by Controlling Post-Deposition Ink Contraction",
         NIP & Digital Fabrication Conference, 2014 Digital Fabrication and Digital Printing: NIP30 Technical Program and Proceedings 447-450.

 

C20.  Pit Teunissen, Eric Rubingh, Tim van Lammeren, Robert Abbel, Pim Groen,
         "Inkjet Printing as a Roll-to-Roll Compatible Technology for the Production of Large Area Electronic Devices on a Pre-Industrial Scale",
         NIP & Digital Fabrication Conference, 2014 International Conference on Digital Printing Technologies, 395-398.

 

C21.  H. Khanbareh, S. van der Zwaag and W.A. Groen,
         "Piezoelectric and Pyroelectric Properties of Flexible PT-PEO Composites",
         Proceeding Electroceramics 14, Romania 2014.

 

C22. D.B. Deutz, E. Tempelman, S. van der Zwaag and W.A. Groen

         “Piezoelectric lead zirconium titanate composite touch sensors for integration with flexible OLED technology",
         Proceedings European Conference on Application of Polar Dielectrics 2014, July 10, Vilnius, Lithuania.

 

C23.  H. Khanbareh, D.B. Deutz, S. van der Zwaag, W.A. Groen,
         “Materials selection for piezo- and pyroelectric energy harvesting,“ 

         ICAST2014: 25nd International Conference on Adaptive Structures and Technologies, October 6-8th, 2014, The Hague, The Netherlands.

 

C24.  T. Vuorinen, M. Janka, J. E. Rubingh, S. Tuukkanen, P. Groen and D. Lupo,
         ”Spray coating of self-aligning passivation layer for metal grid lines”,
         Proceedings of Electronic System-Integration Technology Conference (ESTC), 2014 5th. IEEE, 2014., 10.1109/ESTC.2014.6962776.

 

 

                        

Patents

 

1)              W.A. Groen, M.J. Kraan en G. de With,

                 “Magnesium silicium nitride ceramics”.

                  DE69407832, EP611739, JP6263543, US5411924

 

2)              W.A. Groen, M.J. Kraan P.F. van Hal en G. de With,

                 “Al-O-C-N substrate for Si-technology”.

                  DE69503472T2 , EP743929, JP9509394, US5635429, US5571757

 

3)              W.A. Groen,

                 “Indiumhaltiger oxidkeramischer Thermistor”.

                  DE19622112, EP810612, JP10092609 , US5976421

 

4)              W.A. Groen,

                 “Selten-erd-metallhaltiger hoch temperatur-thermistor“.

                 DE19621934 , EP0810611B1 , JP10092609, US05955937

 

5)              W.A. Groen and V.R.C.M.J. Sillen,

                 ”Schaltungsanordnung mit einem SMD-bauelement, insbesondere Temperatursensor und Verfahren zur Herstellung eines Temperatur

                 Sensors“.

                 DE19736855, EP899550, JP11148873, US6515572

 

6)              S. Kordic, K. Mutsaers, M. Klee and W.A. Groen,

                 “Semiconductor device and method for manufacturing such a device”.

                 EP0968529, US6201291

 

7)              C.R. Ronda, C.J.M. Denissen, V. Weiler and W.A. Groen,

                 “Low pressure mercury vapor discharge lamp with electrode shield”.

                  DE69915966, EP995222, JP20025156352, US6274981

 

8)              A. Nellissen, P. van Oppen, H. Loebl, M. Klee, W.A. Groen and N. van Veen,

                 “Thin film capacitor”.

                  EP98204217.8, US6337790

 

9)              G. Greuel, W.A. Groen and S. Schuurman,

                 “Widerstandelement mit Widerstandschichten“.

                  DE19849649.4

 

10)           K. Albertsen and W.A. Groen,

                “Passives Bauelement mit Verbundstoff“.             

                 DE19939483, EP1259968, JP2003516619, US6721164

 

11)          A. Kraus, B. Rausenberger, W.A. Groen and H. Dannert,

               “Niederdruck-Gasentladungslampe mit hoher Leuchtdichte“.

                DE10014407, EP1137050, JP2001291492, US6858985, US2001024090

 

12)           W.A. Groen, P. Huppertz, K. Albertsen and B. Rausenberger,

                “Dielektrische keramische Zusammensetzung“.

                 DE10155593, EP1256971, JP2002352773, US6744204

 

13)           W.A. Groen, B. Rausenberger and K Albertsen,

                “Liquid crystal picture screen with improved backlighting”.

                 DE10126958, EP1263021, JP2003036816, US6713946

 

14)           Norbert Braun, W.A. Groen, A. Kraus, B. Rausenberger, B. Roulevink, J.A. Vorachen,

               “Gas discharge lamp and method of its manufacture”.

                DE10128139, EP1265264, JP2003068193 , US20030034735

 

15)           W.A. Groen and J. Pankert,

                “Gas discharge lamp”.

                 DE10016736.

 

16)           D. Hennings, W.A. Groen, P Schmidt, R. Mauczok, P. Huppertz and B. Schreinemacher, 

                “Dielektrische keramische Zusammensetzung“.

                DE10155593, EP1036777, US5011804.

 

17)           H. Bechtelt, Y. Martynov, W. Busselt, W.A. Groen, P. Huppertz,

                “Display comprising a varistor layer”.

                DE10251583, EP1563715, US20060033856, JP2006505904, AU2003274450.                  

 

18)           D.A. van de Ende and W.A. Groen,

                “Method for manufacturing a mainly film shaped piezoelectric element”.

                WO2010229261; EP2264802-A1; WO2010147470-A1; EP2443678-A1

 

19)           D.A. van de Ende and W.A. Groen,

                "Piezoelectric Structure (short fiber based piezoelectric energy scavenger)."

                EP2466661-A1; WO2012087118-A1. 

20)           Redha Bella, Mahmoud M. Almadhoun, Jesus Alfonso Caraveo Frescas, Ibrahim Al-Howaish, N. K. James, 

                S. van der Zwaag, J. Khaliq and W.A. Groen,
                “Method for making high piezoelectric voltage coefficient Lead free piezoelectric composites, “
                Filed priority date.

 

Name author: D.B. Deutz
© 2015 TU Delft

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